Age and early metamorphic history of the Sanbagawa belt: Lu–Hf and P–T constraints from the Western Iratsu eclogite

Two distinct age estimates for eclogite-facies metamorphism in the Sanbagawa belt have been proposed: (i) c.  120–110 Ma based on a zircon SHRIMP age for the Western Iratsu unit and (ii) c.  88–89 Ma based on a garnet–omphacite Lu–Hf isochron age from the Seba and Kotsu eclogite units. Despite the contrasting estimates of formation ages, petrological studies suggest the formation conditions of the Western Iratsu unit are indistinguishable from those of the other two units—all ∼20 kbar and 600–650 °C. Studies of the associated geological structures suggest the Seba and Western Iratsu units are parts of a larger semi-continuous eclogite unit. A combination of geochronological and petrological studies for the Western Iratsu eclogite offers a resolution to this discrepancy in age estimates. New Lu–Hf dating for the Western Iratsu eclogite yields an age of 115.9 ± 0.5 Ma that is compatible with the zircon SHRIMP age. However, petrological studies show that there was significant garnet growth in the Western Iratsu eclogite before eclogite facies metamorphism, and the early core growth is associated with a strong concentration of Lu. Pre-eclogite facies garnet (Grt1) includes epidote–amphibolite facies parageneses equilibrated at 550–650 °C and ∼10 kbar, and this is overgrown by prograde eclogite facies garnet (Grt2). The Lu–Hf age of c.  116 Ma is strongly skewed to the isotopic composition of Grt1 and is interpreted to reflect the age of the pre-eclogite phase. The considerable time gap ( c.  27 Myr) between the two Lu–Hf ages suggests they may be related to separate tectonic events or distinct phases in the evolution of the Sanbagawa subduction zone.     

Sources and sinks of sea salt in a newfoundland blanket bog

Over an oceanic peatland, the concentration of Na in fog averaged 38.1 mgl^?1 compared with 1.8 mgl^?1 in rain, resulting in a significant flux of mineral elements to the surface. Between 16 May and 20 June 1990 the average mass flux of Na to the bog surface by fog, rain, and dry deposition was 21.9, 10.4 and 7.0 mg m^?2 d^?1. There was little long-term storage of Na within the peatland system, where Na losses measured in stream runoff averaged 34.8 mg m² d^?1, and deep groundwater losses 4 mg m^?2 d^?1. Calcium and Mg were preferentially retained in the organic soil, whereas K was relatively mobile. Potassium tended to become concentrated in the unsaturated zone. Stream runoff had a consistently higher pH than groundwater, corresponding to higher Ca and Mg concentrations, which may have been from mineral sources in the headwater ponds. Otherwise, the stream water chemistry was closely related to groundwater in the upper layers of the peat deposit.     

Interpretation of aeromagnetic data across the central crystalline shield area of Nigeria

Summary. A residual map of the total magnetic field (above 25 000 nT base) is presented for a portion of the central crystalline shield area of Nigeria and overlapping small portions of the Chad basin and the Benue rift (8°30'−12° 00'lat, and 7°−10°30' long). The map (based on a dataset digitized from recently released aeromagnetic sheets of Nigeria) leads to four results. (1) A magnetic boundary, evident on the map, separates the Younger Granite complexes into two groups. The groups are petrologically different, and the boundary may be a fault line with uplift to the south. (2) South of the boundary the map is dominated by a system of sub-parallel anomalies striking NE–SW, possibly representing major tectonic trends, and a set of fractures through which the Younger Granite complexes were intruded. The trend of the system parallels the Benue rift and lineaments in the oceanic crust off West Africa. (3) Negative magnetic anomalies lie over most of the known ring complexes, and over some suspected buried ring complexes and other intrusions. (4) 2½-and 3-D modelling shows that the larger complexes extend to 12 km depth, and the smaller ones to 6 km. They have nearly vertical sides, and magnetization contrasts range from 0.3 to 0.5 A m⁻¹.     

INVERSE DDA OF A SYSTEM OF BLOCKS IN SPHERE COORDINATES

1　IntroductionDiscontinuousDeformationAnalysis(DDA)developedbyShiin 1 980’s[1 ,2 ] maybeusedtocalculatethedeformationanddisplacementsinamulti blocksystemandtoanalyzetherelationbe tweenforcesanddisplacementsinthesystem .Ifthesurveydisplacementofeverypointordirectionisknown,alldisplacementsanddeformationsofblocks,eventheglide ,theclosureandthestretchoftheboundary planeofblocks ,canbecalculated .TheresultisoptimallyfittedaccordingtotheLeastSquarePrinciple.DDAismainlyusedinrockblockssystems…     

Crustal and upper mantle structures of the brazilian coast

The Rayleigh wave phase and group velocities in the period range of 24–39 sec, obtained from two earthquakes which occurred in northeastern brazil and which were recorded by the Brazilian seismological station RDJ (Rio de Janeiro), have been used to study crustal and upper mantle structures of the Brazilian coastal region. Three crustal and upper mantle models have been tried out to explain crustal and upper mantle structures of the region. The upper crust has not been resolved, due basically to the narrow period range of the phase and group velocities data. The phase velocity inversions have exhibited good resolutions for both lower crust and upper mantle, with shear wave velocities characteristic of these regions. The group velocity data inversions for these models have showed good results only for the lower crust. The shear wave velocities of the lower crust (3.86 and 3.89 km/sec), obtained with phase velocity inversions, are similar to that (=3.89 km/sec) found byHwang (1985) to the eastern South American region, while group velocity inversions have presented shear velocity (=3.75 km/sec) similar to that (=3.78 km/sec) found byLazcano (1972) to the Brazilian shield. It was not possible to define sharply the crust-mantle transition, but an analysis of the phase and group velocity inversions results has indicated that the total thickness of the crust should be between 30 and 39 km. The crustal and upper mantle model, obtained with phase velocity inversion, can be used as a preliminary model for the Brazilian coast.     

Temperature of the Icelandic crust: Inferred from electrical conductivity, temperature surface gradient, and maximum depth of earthquakes

Two different models of the structure of the Icelandic crust have been presented. One is the thin-crust model with a 10–15 km thick crust beneath the axial rift zones, with an intermediate layer of partially molten basalt at the base of the crust and on the top of an up-domed asthenosphere. The thick-crust model assumes a 40 km thick and relatively cold crust beneath central Iceland. The most important and crucial parameter to distinguish between these different models is the temperature distribution with depth. Three methods are used to estimate the temperature distribution with depth. First, the surface temperature gradient measured in shallow wells drilled outside geothermal areas. Second, the thickness of the seismogenic zone which is associated with a 750 °C isothermal surface. Third, the depth to a layer with high electrical conductivity which is associated with partially molten basalt with temperature around 1100 °C at the base of the crust. Combination of these data shows that the temperature gradient can be assumed to be nearly linear from the surface down to the base of the crust. These results are strongly in favour of the thin-crust model. The scattered deep seismic reflectors interpreted as Moho in the thick-crust model could be caused by phase transitions or reflections from melt pockets in the mantle.     

Stratigraphy and sedimentation rates of Upper Cretaceous deep-water systems of the Rhenodanubian Group (Eastern Alps, Germany)

In the Bavarian Alps (Germany), west of the Isar River, the abyssal deposits of the Lower Barremian to Upper Campanian Rhenodanubian Group consist of siliciclastic and calcareous turbidites alternating with hemipelagic non-calcareous mudstones. The up to 1500-m-thick succession, deposited in the Penninic Basin to the south of the European Plate, is characterized by a low mean sedimentation rate (c. 25 mm kyr⁻¹) over 60 million years. Palaeocurrents and turbidite facies distribution patterns suggest that sedimentation occurred on a weakly inclined abyssal plain. The highest sedimentation rates (up to 240 mm kyr⁻¹) were associated with the calcareous mud turbidites of the newly defined Röthenbach Subgroup, which includes the Piesenkopf, Kalkgraben and Hällritz formations (Middle Coniacian to Middle Campanian). These calcareous turbidites prograded from the west, and interfinger towards the east with red hemipelagic claystone. A high sea level presumably favoured pelagic carbonate production and accumulation on the shelves and on internal platforms in the western part of the basin, whereas siliciclastic shelves with steep slope angles have bordered the eastern part of the basin, where a dearth of turbidite sedimentation and increased Cretaceous oceanic red beds deposition occurred. In contrast to the eustatically-induced Middle Coniacian to Lower Campanian Cretaceous oceanic red beds (calcareous nannoplankton zones CC14 to CC18), red hemipelagites of Early Cenomanian age (upper part of calcareous nannoplankton zone CC9) and early Late Campanian age (upper part of zone CC21 and zone CC22) are interpreted as the result of regional tectonic activity.     

The role of heterogeneous strain in the development and preservation of a polymetamorphic record in high-P granulites, western Canadian Shield

Mafic rocks in the Chipman domain of the Athabasca granulite terrane, western Canadian Shield, provide the first well‐documented record of two distinct high‐P granulite facies events in the same domain in this region. Textural relations and the results of petrological modelling (NCFMASHT system) of mafic granulites are interpreted in terms of a three‐stage tectonometamorphic history. Stage 1 involved development of the assemblage Grt + Cpx + Qtz ± Pl (M₁) from a primary Opx‐bearing igneous precursor at conditions of 1.3 GPa, 850–900 °C. Field and microstructural observations suggest that M₁ developed synchronously with an early S₁ gneissic fabric. Stage 2 is characterized by heterogeneous deformation (D₂) and synkinematic partial retrogression of the peak assemblage to an amphibole‐bearing assemblage (M₂). Stage 3 involved a third phase of deformation and a return to granulite facies conditions marked by the prograde breakdown of amphibole (Amph₂) to produce matrix garnet (Grt_3a) and the coronitic assemblage Cpx_3b + Opx_3b + Ilm_3b + Pl_3b (M_3b) at 1.0 GPa, 800–900 °C. M₁ and M_3b are correlated with 2.55 and 1.9 Ga metamorphic generations of zircon, respectively, which were dated in a separate study. Heterogeneous strain played a crucial role in both the development and preservation of these rare examples of multiple granulite facies events within single samples. Without this fortuitous set of circumstances, the apparent reaction history could have incorrectly led to an interpretation involving a single‐cycle high‐grade event. The detailed P–T–t–D history constructed for these rocks provides the best evidence to date that much of the east Lake Athabasca region experienced long‐term lower crustal residence from 2.55 to 1.9 Ga, and thus the region represents a rare window into the reactivation and ultimate stabilization processes of cratonic lithosphere.     

Partial Melting and Counterclockwise P T Path of Subducted Oceanic Crust (Sierra del Convento Melange, Cuba)

Partial melting of subducted oceanic crust has been identifiedin the Sierra del Convento mélange (Cuba). This serpentinite-matrixmélange contains blocks of mid-ocean ridge basalt (MORB)-derivedplagioclase-lacking epidote ± garnet amphibolite intimatelyassociated with peraluminous trondhjemitic–tonalitic rocks.Field relations, major element bulk-rock compositions, mineralassemblages, peak metamorphic conditions (c. 750°C, 14–16kbar), experimental evidence, and theoretical phase relationssupport formation of the trondhjemitic–tonalitic rocksby wet melting of subducted amphibolites. Phase relations andmass-balance calculations indicate eutectic- and peritectic-likemelting reactions characterized by large stoichiometric coefficientsof reactant plagioclase and suggest that this phase was completelyconsumed upon melting. The magmatic assemblages of the trondhjemitic–tonaliticmelts, consisting of plagioclase, quartz, epidote, ±paragonite, ± pargasite, and ± kyanite, crystallizedat depth (14–15 kbar). The peraluminous composition ofthe melts is consistent with experimental evidence, explainsthe presence of magmatic paragonite and (relict) kyanite, andplaces important constraints on the interpretation of slab-derivedmagmatic rocks. Calculated P–T conditions indicate counterclockwiseP–T paths during exhumation, when retrograde blueschist-faciesoverprints, composed of combinations of omphacite, glaucophane,actinolite, tremolite, paragonite, lawsonite, albite, (clino)zoisite,chlorite, pumpellyite and phengite, were formed in the amphibolitesand trondhjemites. Partial melting of subducted oceanic crustin eastern Cuba is unique in the Caribbean realm and has importantconsequences for the plate-tectonic interpretation of the region,as it supports a scenario of onset of subduction of a youngoceanic lithosphere during the early Cretaceous (c. 120 Ma).The counterclockwise P–T paths were caused by ensuingexhumation during continued subduction. KEY WORDS: amphibolite; Cuba; exhumation; partial melting; trondhjemite; subduction     

Trace Element Partitioning and Accessory Phase Saturation during H2O-Saturated Melting of Basalt with Implications for Subduction Zone Chemical Fluxes

Experimental phase equilibrium and trace element partitioningdata are reported for H₂O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO₂ contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H₂O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite